Here's a 列表 of all the great musics that we heard everytime that Blair and Chuck were on tv. :)
Episode 1.01 - Pilot
"If It's Lovin' That 你 Want (Part 2)" 由 蕾哈娜 Feat. Corey Gunz
Dinner Party, before Blair takes Nate into her room
"What Goes Around...Comes Around" 由 Justin Timberlake
Dinner Party, after Serena leaves
"Hard to Live in the City" 由 Albert Hammond Jr.
Limo ride to the "kiss of the lips" party
"The Gift" 由 天使 & Airwaves
Blair and Chuck watch Serena leave with Dan
Episode 1.02 - The Wild Brunch
"Tell Me 'Bout It" 由 Joss Stone
Blair, Chuck and the group having Brunch
"The 皇后乐队 And I" 由 Gym Class Heroes
Chuck gives Blair the key to his suite
"Shut Up And Drive" 由 蕾哈娜
Blair reveals Serena's secret infront of Dan and the group
Episode 1.03 - Poison Ivy
"Glamorous" 由 The Constance Billard Choir
Everyone walking into school
Episode 1.06 - The Handmaiden's Tale
"Take it to the top" 由 5 Alarm
Blair and Chuck at the ball
Episode 1.07 - Victor, Victrola
"So They Say" 由 Classic
Chuck asks Blair about his idea
"Stripper" 由 Soho Dolls
Chuck watching Blair at Victrola
"With Me" 由 Sum 41
Blair and Chuck in the limo!
Episode 1.08 - Seventeen Candles
"One Week Of Danger" 由 The Virgins
Blair flashback to the Limo.
Blair tells Chuck to leave her alone.
Serena sees Blair and Chuck kissing
"Love Is Colder Than Death" 由 The Virgins
Chuck arrives at Blair's party
"How Does It Feel?" 由 Eskimo Joe
Blair runs off from her birthday cake
"Radio Christiane" 由 The Virgins
Chuck brings Blair her gift
Episode 1.10 - Hi, Society
"You're a Wolf" 由 Sea Wolf
Blair and Chuck making out
"Secret" 由 The Pierces
Everyone dancing at the ball
"Three Wishes" 由 The Pierces
Chuck and Blair dance at the ball
Episode 1.12 - School Lies
"Ooh Yeah" 由 Moby
Blair and Chuck 由 the pool
"Come Flash All 你 Ladies" 由 The Filthy Youth
Blair takes the key from Chuck
"Orange" 由 The Filthy Youth
Chuck confronts Blair
Episode 1.13 - A Thin Line Between Chuck and Nate
"You'll Change" 由 Machine Translations
Chuck watches Nate and Blair together
"The Air We Breathe" 由 The Figurines
Blair thinks back to the limo
Episode 1.17 - Woman on the Verge
"Fight Song" 由 The Republic Tigers
Serena, Blair & Chuck arrive at the rehearsal dinner
"Everytime" 由 林肯 Hawk
Nate, Blair & Chuck arrive at the concert
Episode 1.18 - Much 'I Do' About Nothing
"The Ice Is Getting Thinner" 由 Death Cab For Cutie
Chuck's speech and Blair/Chuck dancing
Source: link
Episode 1.01 - Pilot
"If It's Lovin' That 你 Want (Part 2)" 由 蕾哈娜 Feat. Corey Gunz
Dinner Party, before Blair takes Nate into her room
"What Goes Around...Comes Around" 由 Justin Timberlake
Dinner Party, after Serena leaves
"Hard to Live in the City" 由 Albert Hammond Jr.
Limo ride to the "kiss of the lips" party
"The Gift" 由 天使 & Airwaves
Blair and Chuck watch Serena leave with Dan
Episode 1.02 - The Wild Brunch
"Tell Me 'Bout It" 由 Joss Stone
Blair, Chuck and the group having Brunch
"The 皇后乐队 And I" 由 Gym Class Heroes
Chuck gives Blair the key to his suite
"Shut Up And Drive" 由 蕾哈娜
Blair reveals Serena's secret infront of Dan and the group
Episode 1.03 - Poison Ivy
"Glamorous" 由 The Constance Billard Choir
Everyone walking into school
Episode 1.06 - The Handmaiden's Tale
"Take it to the top" 由 5 Alarm
Blair and Chuck at the ball
Episode 1.07 - Victor, Victrola
"So They Say" 由 Classic
Chuck asks Blair about his idea
"Stripper" 由 Soho Dolls
Chuck watching Blair at Victrola
"With Me" 由 Sum 41
Blair and Chuck in the limo!
Episode 1.08 - Seventeen Candles
"One Week Of Danger" 由 The Virgins
Blair flashback to the Limo.
Blair tells Chuck to leave her alone.
Serena sees Blair and Chuck kissing
"Love Is Colder Than Death" 由 The Virgins
Chuck arrives at Blair's party
"How Does It Feel?" 由 Eskimo Joe
Blair runs off from her birthday cake
"Radio Christiane" 由 The Virgins
Chuck brings Blair her gift
Episode 1.10 - Hi, Society
"You're a Wolf" 由 Sea Wolf
Blair and Chuck making out
"Secret" 由 The Pierces
Everyone dancing at the ball
"Three Wishes" 由 The Pierces
Chuck and Blair dance at the ball
Episode 1.12 - School Lies
"Ooh Yeah" 由 Moby
Blair and Chuck 由 the pool
"Come Flash All 你 Ladies" 由 The Filthy Youth
Blair takes the key from Chuck
"Orange" 由 The Filthy Youth
Chuck confronts Blair
Episode 1.13 - A Thin Line Between Chuck and Nate
"You'll Change" 由 Machine Translations
Chuck watches Nate and Blair together
"The Air We Breathe" 由 The Figurines
Blair thinks back to the limo
Episode 1.17 - Woman on the Verge
"Fight Song" 由 The Republic Tigers
Serena, Blair & Chuck arrive at the rehearsal dinner
"Everytime" 由 林肯 Hawk
Nate, Blair & Chuck arrive at the concert
Episode 1.18 - Much 'I Do' About Nothing
"The Ice Is Getting Thinner" 由 Death Cab For Cutie
Chuck's speech and Blair/Chuck dancing
Source: link